Haynes do a workshop manual for the C2, as an example on ebay http://www.ebay.co.uk/itm/5635-Haynes-Citroen-C2-2003-2010-53-to-60-Service-Manual-/122270478392?_trksid=p2141725.m3641.l6368 There is also the Citroen service box which can be obtained through ebay. Does the radiator fan run when the air con is switched on - if not the air con will not work ? From the service box procedures, there should be a high temperature warning at 118°C, the thermostat should start to open at 89°C and be full open by 101°C. I could not find the fan settings but on our C3 it would start at 96°C and cut out at 94°C. I do not know what the thermostat wire is for, maybe there is a second temp sensor - if you have a part number for the thermostat it could be looked up.